Lithium-ion batteries don’t work well in the cold − a battery researcher explains the chemistry at low temperatures

Why do batteries lose charge more quickly when it’s cold? Halfpoint Images/Moment

Rechargeable batteries are great for storing energy and powering electronics from smartphones to electric vehicles. In cold environments, however, they can be more difficult to charge and may even catch on fire.

I’m a mechanical engineering professor who’s been interested in batteries since college. I now lead a battery research group at Drexel University.

In just this past decade, I have watched the price of lithium-ion batteries drop as the production market has grown much larger. Future projections predict the market could reach thousands of GWh per year by 2030, a significant increase.

But, lithium-ion batteries aren’t perfect – this rise comes with risks, such as their tendency to slow down during cold weather and even catch on fire.

Behind the Li-ion battery

The electrochemical energy storage within batteries works by storing electricity in the form of ions. Ions are atoms that have a nonzero charge because they have either too many or not enough electrons.

When you plug in your electric car or phone, the electricity provided by the outlet drives these ions from the battery’s positive electrode into its negative electrode. The electrodes are solid materials in a battery that can store ions, and all batteries have both a positive and a negative electrode.

Electrons pass through the battery as electricity. With each electron that passes to one electrode, a lithium ion also passes into the same electrode. This ensures the balance of charges in the battery. As you drive your car, the stored ions in the negative electrode move back to the positive electrode, and the resulting flow of electricity powers the motor.

When a lithium-ion battery delivers energy to a device, lithium ions – atoms that carry an electrical charge – move from the negative electrode, the anode, to the positive electrode, the cathode. The ions move in reverse when recharging.
Argonne National Laboratory, CC BY-NC-SA

While AA or AAA batteries can power small electronics, they can be used only once and cannot be charged. Rechargeable Li-ion batteries can operate for thousands of cycles of full charge and discharge. For each cycle, they can also store a much higher amount of charge than an AA or AAA battery.

Since lithium is the lightest metal, it has a high specific capacity, meaning it can store a huge amount of charge per weight. This is why lithium-ion batteries are useful not just for portable electronics but for powering modes of transportation with limited weight or volume, such as electric cars.

Battery fires

However, lithium-ion batteries have risks that AA or AAA batteries don’t. For one, they’re more likely to catch on fire. For example, the number of electric bike battery fires reported in New York City has increased from 30 to nearly 300 in the past five years.

Lots of different issues can cause a battery fire. Poorly manufactured cells could contain defects, such as trace impurities or particles left behind from the manufacturing process, that increase the risk of an internal failure.

The lithium-ion batteries in electric vehicles have a higher risk of catching on fire when it’s cold out.
Orange County Sheriff’s Department/National Transportation Safety Board via AP

Climate can also affect battery operation. Electric vehicle sales have increased across the U.S., particularly in cold regions such as the Northeast and Midwest, where the frigid temperatures can hinder battery performance.

Batteries contain fluids called electrolytes, and cold temperatures cause fluids to flow more slowly. So, the electrolytes in batteries slow and thicken in the cold, causing the lithium ions inside to move slower. This slowdown can prevent the lithium ions from properly inserting into the electrodes. Instead, they may deposit on the electrode surface and form lithium metal.

The molecules in fluids move slower at colder temperatures – the same thing happens inside batteries.

If too much lithium deposits on the electrode’s surface during charging, it may cause an internal short circuit. This process can start a battery fire.

Making safer batteries

My research group, along with many others, is studying how to make batteries that operate more efficiently in the cold.

For example, researchers are exploring swapping out the usual battery electrolyte and replacing it with an alternative electrolyte that doesn’t thicken at cold temperatures. Another potential option is heating up the battery pack before charging so that the charging process occurs at a warmer temperature.

My group is also investigating new types of batteries beyond lithium ion. These could be battery types that are more stable at wider temperature ranges, types that don’t even use liquid electrolytes at all, or batteries that use sodium instead of lithium. Sodium-ion batteries could work well and cost less, as sodium is a very abundant resource.

Solid-state batteries use solid electrolytes that aren’t flammable, which reduces the risk of fire. But these batteries don’t work quite as well as Li-ion batteries, so it’ll take more research to tell whether these are a good option.

Lithium-ion batteries power technologies that people across the country use every day, and research in these areas aims to find solutions that will make this technology even safer for the consumer.

Wesley Chang receives funding from Solid Energy Systems, Inc., Electric Power Research Institute, Drexel University. Wesley Chang consults for The Electrochemical Society.